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Foam premixes with improved processability |
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Atofina Chemicals Inc., the United States, has been granted a
patent for a method for improving the processability of foam
premixes containing HFC and/or pentane-based blowing agents in
polyols. The method comprises adding
trans-1,2-dichloroethylene to the premix in an amount
effective, which is dependent on the specific blowing agent
and the type of polyols, to enhance the processability. The
premixes can be converted into polyurethane foams by using
conventional techniques, such as hand-mixing, high-pressure
impingement, low-pressure mechanical mixing, etc. Auxiliary
blowing agents such as water, HCFCs or and
hydrochlorocarbons may also be present with the HFC and/or
pentane blowing agents. The other components of the premix and
foam formulations may be the conventionally used ones such as
fire retardants and surfactants.
The compatibility of HFC blowing agents (245fa and 365mfc)
with and without trans-1,2 was tested in polyester polyol.
When 39 parts of 245fa was added to 100 parts of the polyester
polyol without trans-1,2, phase separation occurred. When
trans-1,2 was added to 245fa in a 50/50 weight ratio, a
homogeneous, one-phase polyol mixture was obtained at a level
equivalent to about 50 parts of 245fa to 100 parts polyol.
Similar results were found also with 365mfc.
Website:
www.freepatentsonline.com |
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Moulded polyurethane foam system with HFC blowing
agents |
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Renosol Corporation, the United States, has obtained a patent
on a moulded polyurethane foam system that uses
hydrofluorocarbons and alkane hydrocarbons as the blowing
agents. The moulded polyurethane foam products made using this
system have a high-density integral skin and a low density
core. The patented process involves reacting an isocyanate and
a polyol in the presence of a blowing agent, which includes
HFC-134a alone or a mixture of tetrafluoroethane (HFC-134a)
with one or more of the following: alkanes (such as
methylbutane, pentane and heptane) and other inert volatile
organic compounds with boiling points in the 15-100C range
(such as pentene and acetone). The preferred HFC used in the
present invention, tetrafluoroethane, has zero ozone depletion
potential (ODP), and offers reduced toxicity, improved in-use
stability and zero risk of inflammability or smog production.
Website:
www.freepatentsonline.com |
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Environmentally safe surfboard foam blanks |
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Glory Foam, Mexico, has announced a significant breakthrough
in environmentally safer foam surfboard blanks with the
unveiling of its new PUR Foam product. PUR Foam is an
environmentally safer surfboard foam that also maintains a
bright white appearance. The foam production using the
comparatively safer PMDI technology does not involve bleaches,
pigments, additives or enhancers. The tiny bubbles in the cell
structure refract light and make the foam appear bright white.
The process uses the renewable plant material, namely sugar,
as a base. The blowing agent employed has zero ozone depletion
potential and global warming potential. The production process
also eliminates the need for release papers, which contribute
to landfill trash, commonly used in other production methods.
PUR Foam maintains a uniform tight cell structure, and will
not yellow, chunk or tear. The light and flexible blank does
not contain pour lines and hence, the foam accepts tints well.
Website:
www.globalsurfnews.com |
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CO2-blown polyurethane packaging foam |
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E.R. Carpenter Company Inc., the United States, has patented a
method of preparing polyurethane foam for dispensing into a
container as packaging for shipping. A notable feature of the
invention is that the temperature of the polyurethane foam
being dispensed into the container is lower than other
comparable systems, as is the maximum reaction exotherm
temperature. The method involves reacting polymeric isocyanate
and polyoxyalkylated polyol precursors in the presence of
water as the foam blowing agent. A nucleating agent is present
in at least one of the precursors in an amount sufficient to
reduce the dispensing temperature of the foam reaction
product. Incorporation of a nucleating agent into the
isocyanate and polyol resin components results in a carbon
dioxide (CO2) blown polyurethane packaging foam preferably
having a density of 0.2-2.0 lb/ft3.
Website:
www.freepatentsonline.com |
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Microcellular foam using polymer surfactants and
CO2 |
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Researchers at the University of North Carolina (UNC) at
Chapel Hill, the United States, have developed a method of
making microcellular foam, using carbon dioxide (CO2) as a
blowing agent and either a thermoplastic resin or resin blend
in conjunction with non-ionic polymeric surfactant. The method
could be used in the production of microcellular foamed
polymers/polymer blends for industrial thermoplastic
applications.
Production of structural and other conventional foams
typically employ physical blowing agents and semi-crystalline
polymers. However, semi-crystalline polymers present various
processing challenges, particularly when producing
microcellular foams using a continuous processing, because of
the small size of the cell walls. A small defect in the cell
wall could form a weak point in the structure. Producing
various foamed semi-crystalline thermoplastics such as (poly)
vinylidene fluoride in a continuous process has also been a
problem. As the material exits the nozzle, the extrudate
becomes brittle and breaks up into fine powder. This is most
significant in the formation of microcellular foams, where the
large number of small distributed cells causes the cell walls
of the foamed materials to be significantly thinner than those
of conventional foams.
The UNC method involves essentially three components: a
thermoplastic polymeric resin or blend of thermoplastic
polymeric resins; compressed high-pressure CO2 as a blowing
agent; and a polymeric non-ionic surfactant used to reduce the
surface tension between the thermoplastic resins and CO2. The
combination of blended material and surfactant modifies the
final foam microstructure and enhances blend miscibility. The
polymeric surfactant also reduces viscosity.
Website:
www.ibridgenetwork.org |
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