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Recycling of PlayStation consoles |
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The Electronic
Waste Company in the United Kingdom has announced that it is
to carry out the first stage of recycling one of the worlds
most pioneering and popular computer games consoles the Sony
PlayStation. It has signed contracts with Sony Computer
Entertainment Europe to shred and dispose of the plastic cases
of the consoles an estimated 250 tonnes or 300,000 cases in
the first year alone for Sony operations in Europe.
Routes for the recycled plastic have already been already
identified as pens, chairs, etc. The Electronic Waste Company
has significantly invested in new machinery, which can process
a range of plastics and generate high-quality materials ready
for the manufacture of new products. The machinery can process
plastics ranging from thin films to the thickest of
polyurethanes. The company will ensure 100 per cent reuse or
recycle of this equipment; nothing collected or brought to the
company will be sent to landfill. It is now developing
processes to remove other recyclable components such as
clips and foam from the PlayStation casings.
Source:
www.mcvuk.com
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A commercial recycling process for electronics waste |
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Plastic Herverwerking Brabant BV (PHB), a Dutch plastic
recycling firm, has become the first supplier in the world of
a complete commercial altered-density-media system for
separating the plastics in waste electrical and electronic
equipment (WEEE). PHB is operating a WEEE recycling system
with a capacity of 15 million kg/year, averaging about 1,195
kg/h of reclaimed material from 4,990 kg/h of waste input. The
relatively small proportion of recaptured saleable material
pays off because it includes about 10 per cent valuable metals
mostly copper, but also gold. PHB builds commercial
recycling machinery through another company called Envirotec
BV.
The Envirotec line starts with shredded WEEE plastic with more
than half contamination from non-ferrous metals, stones,
polyurethane foam, glass, etc. The waste is fed into a box
where a high-torque rotor with paddles turns at 3,000 rpm to
beat the flakes against a screen cage, removing most of the
surface dirt, sand, rocks and foam in seconds.
Flakes then go onto a large inclined tray with a grooved
surface. Water sluices over the left half of the board,
washing the plastic flakes down. Heavier metals stay in the
grooves and move off to the right. The plastic flakes are then
ground into 10 mm particles in a granulator, and sent to the
first float/sink tank, which is filled with plain water.
Polyethylene (PE) and polypropylene (PP) float off and are
collected. Acrylonitrile butadiene styrene (ABS), polystyrene
(PS) and flame-retardant (FR) materials sink, and are moved
into another tank containing an aqueous solution of 1.035 g/cc
density as well as three rotating drums with paddle vanes. PS
floats in this tank and is collected, while ABS and FR
materials sink. ABS and FR go into a third tank fitted with
four drums having paddle vanes and filled with a water
solution of 1.07 density. Here ABS floats and is collected,
while FR materials sink.
This WEEE recycling process is suitable for appliances that
are free from grease and grime and do not require pre-wash.
The closed-loop system does not change the water column, but
continuously filters out particulates with a fine Nylon mesh
on a revolving belt, which is cleaned at one end by
high-pressure water jets. Contact: Envirotec B.V., Duikerweg
32, 5145 NV Waalwijk, The Netherlands. Tel: +31 (416) 697 445;
Fax: +31 (416) 697 311; E-mail: info@envirotec-rec.com.
Source:
www.allbusiness.com |
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Extraction of chemicals from lithium batteries |
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In Brazil, LG Electronics de So Paulo
Ltda. and Mr. Marcelo Bozzo have jointly patented a process
for extracting the chemical compounds found in secondary
lithium-ion batteries. The process uses relatively low
temperatures and a low-toxicity solvent that is easy to be
obtained and handled. The process consists of six main
stages: (1) opening and separation; (2) extraction of
lithium compounds through an organic solution; (3) positive
electrode dissolution; (4) aluminium separation; (5) cobalt
compounds precipitation; and (6) copper collector separation
(negative electrode).
The process begins with cutting open the battery: the
polymeric body, the metal body, the terminals and the side
nickel tape are separated at this stage and sent to
companies specialized in recycling such components. Both the
electrodes and separators undergo a process for the
extraction of lithium (Li) components. They are placed in a
solution of hydrated alcohol and acetone (5 per cent). They
remain immersed for about two hours, during which time Li
salt extraction occurs. Then the electrodes are removed and
the solution filtered, separating lithium carbonate and
lithium hydroxide, which resulted from the initial reaction,
from the organic solution. The filtrate holds the
alcohol/acetone solution and residues of solvent and battery
electrolyte.
After Li compounds are extracted, the positive electrodes
are immersed in acid aqueous solution for the dissolution of
aluminium and cobalt and lithium oxide. The solution is
filtered: aluminium and cobalt remain in the filtrate.
Ammonium hydroxide (30 per cent) is used for precipitating
aluminium in the filtrate. For the cobalt compound
precipitation, a saturated lithium hydroxide solution is
added, making the solution basic. After the precipitation,
the precipitate is filtered and dried. A hydrochloric acid
solution (5 per cent) is added to the negative electrodes to
remove agglutinant and graffiti. After ten minutes of
stirring, the solution is filtered. The graffiti and the
agglutinant are released, passing through the holes, while
the copper remains in the perforated container. The
agglutinant and graffiti are filtered out, and the acid
solution can be reused in the process for a couple of times.
Contact: LG Electronics de So Paulo Ltda., Avenida Dom
Pedro I, W 7777, Prdio 1 e 2- rea Industrial- Taubat, So
Paulo - CEP 12090-000, Brazil.
Source:
www.wipo.int |
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Rotary thermal oxidizer for battery recycling |
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International Metals
Reclamation Company Inc., the United States, has patented a
rotary thermal oxidizer that removes polymeric and other
non-metal components of exhausted batteries and cells leaving
valuable metals such as nickel, cadmium and iron behind
for subsequent processing.
Pre-heating the sweep gas to a temperature above the
auto-ignition point of the polymers, prior to their
introduction into the oxidizer, and controlling the oxygen
content within the oxidizer, substantially reduces the risks
of explosion and fire associated with the pyro-metallurgical
recycling of the cells. The thermal oxidizer thus includes
provision to pre-heat the sweep gas entering the oxidizer to
adequately heat the cells and initiate polymer combustion
under controlled conditions. A
water spray protects the oxidizer by controlling its internal
temperature. It also controls the combustion of the entrained
polymeric components, thereby avoiding the possibility of
explosions. An explosion plate is included in the discharge
housing as a safety device.
Source:
www.freepatentsonline.com
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Shape memory helps recycling of gadgets |
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Recycling devices built with plastic cases and other
components such as mobile phones, mp3 players and personal
digital assistants is difficult and needs repetitive manual
labour. However, a new approach to creating the fastenings and
tabs for such devices based on the shape-memory effect in
plastics may allow the process to be automated. The approach
proposed by Mr. Habib Hussein and Mr. David Harrison of the
School of Engineering and Design at Brunel University, the
United Kingdom would allow valuable components and metals to
be recovered more efficiently from the millions of devices
discarded every year.
The researchers studied the possibility of Active Disassembly
using Smart Materials, which employs materials that can act
as fasteners within a product and, at products end of life,
can be undone simply by direct heating. This releases the
fasteners, causing the device case to fall apart without
manual intervention. This is an important design feature that
might make recycling electronic devices with plastic cases
much easier. According to the concept of shape memory effect,
materials such as engineering plastics (polymers) can be
fabricated in one shape the unfastened state and then
moulded a second time into a new shape the fastened state.
When the plastic in fastened state is heated, it will revert
to its original unfastened state, because it retains a
molecular memory of its original form.
The researchers have developed a case-fastening device based
on one such shape memory polymer. Their tests demonstrated
that lowering the device at end of life into hot water, leads
to the fasteners reverting to their unfastened state and the
case falling apart on agitation. They have also shown that the
fasteners retain their integrity for at least two years
without falling apart spontaneously.
Source:
www.sciencedaily.com
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